Saturday, June 13, 2009

Pearls and calcareous concretions from other species

Biologically speaking, under the right set of circumstances, almost any shelled mollusk can produce some kind of pearl, however, most of these molluscan pearls have no luster or iridescence. The great majority of mollusk species produce pearls which are not attractive to look at, and are sometimes not even very durable, such that they usually have no value at all, except perhaps to a scientist, a collector, or as a curiosity. These objects used to be referred to as "calcareous concretions" by some gemologists, even though a malacologist would still consider them to be pearls. Valueless pearls of this type are sometimes found in edible mussels, edible oysters, escargot snails, and so on. Kenneth Scarrat, director of GIA Bangkok, has recently argued for changes to current nomenclature. He argues conch "pearls" should be referred to (and various other types of mollusc pearls) as simply pearls, not "calcareous concretions".[5]
 
Shell of the Indian volute or bailer shell Melo melo, surrounded by a number of Melo pearls

A few species produce pearls that can be of interest as gemstones. These species include the bailer shell Melo (genus), the giant clam Tridacna, various scallop species, Pen shells Pinna (genus), and abalones. Another example is the conch pearl (sometimes referred to simply as the 'pink pearl'), which is found very rarely growing between the mantle and the shell of the queen conch or pink conch, Strombus gigas, a large sea snail or marine gastropod from the Caribbean Sea. These pearls, which are often pink in color, are a by-product of the conch fishing industry, and the best of them display a shimmering optical effect related to chatoyance known as 'flame structure'.

Somewhat similar gastropod pearls, this time more orange in hue, are (again very rarely) found in the horse conch Pleuroploca gigantea.
 
Largest known pearl from a giant clam

The largest pearl known, was found in the Philippines in 1934. It is a naturally-occurring, non-nacreous, calcareous concretion from a giant clam. Because it did not grow in a pearl oyster it is not pearly, instead it has a porcellaneous surface. In other words, it is glossy like a china plate. Other pearls from giant clams are known to exist, but this is a particularly large one. The pearl weighs 14 lb (6.4 kg) and was supposedly first discovered by an anonymous Filipino Muslim diver off the island of Palawan in 1934. According to the legend as it is currently told, a Palawan chieftain gave the pearl to Wilbur Dowell Cobb in 1936 as a gift for having saved the life of his son. The pearl had been named the "Pearl of Allah" by the Muslim tribal chief, because it resembled a turbaned head. Another even more elaborate legend says that this object is actually the Pearl of Lao-Tzu, a cultured pearl created with a carved amulet and then supposedly progressively grafted into several giant clams, before supposedly being lost due to a shipwreck in 1745. [6] This legend has been discredited, however because this pearl is indeed the product of a giant clam, Tridacna gigas, which cannot be grafted. The pearl is also a whole pearl, not a mabe pearl, and whole pearl culturing technology is only 100 years old. [7]

Wednesday, April 1, 2009

Pearls and calcareous concretions from other species


Biologically speaking, under the right set of circumstances, almost any shelled mollusk can produce some kind of pearl, however, most of these molluscan pearls have no luster or iridescence. The great majority of mollusk species produce pearls which are not attractive to look at, and are sometimes not even very durable, such that they usually have no value at all, except perhaps to a scientist, a collector, or as a curiosity. These objects used to be referred to as "calcareous concretions" by some gemologists, even though a malacologist would still consider them to be pearls. Valueless pearls of this type are sometimes found in edible mussels, edible oysters, escargot snails, and so on. Kenneth Scarrat, director of GIA Bangkok, has recently argued for changes to current nomenclature. He argues conch "pearls" should be referred to (and various other types of mollusc pearls) as simply pearls, not "calcareous concretions".[5]
 
Shell of the Indian volute or bailer shell Melo melo, surrounded by a number of Melo pearls

A few species produce pearls that can be of interest as gemstones. These species include the bailer shell Melo (genus), the giant clam Tridacna, various scallop species, Pen shells Pinna (genus), and abalones. Another example is the conch pearl (sometimes referred to simply as the 'pink pearl'), which is found very rarely growing between the mantle and the shell of the queen conch or pink conch, Strombus gigas, a large sea snail or marine gastropod from the Caribbean Sea. These pearls, which are often pink in color, are a by-product of the conch fishing industry, and the best of them display a shimmering optical effect related to chatoyance known as 'flame structure'.

Somewhat similar gastropod pearls, this time more orange in hue, are (again very rarely) found in the horse conch Pleuroploca gigantea.
 
Largest known pearl from a giant clam

The largest pearl known, was found in the Philippines in 1934. It is a naturally-occurring, non-nacreous, calcareous concretion from a giant clam. Because it did not grow in a pearl oyster it is not pearly, instead it has a porcellaneous surface. In other words, it is glossy like a china plate. Other pearls from giant clams are known to exist, but this is a particularly large one. The pearl weighs 14 lb (6.4 kg) and was supposedly first discovered by an anonymous Filipino Muslim diver off the island of Palawan in 1934. According to the legend as it is currently told, a Palawan chieftain gave the pearl to Wilbur Dowell Cobb in 1936 as a gift for having saved the life of his son. The pearl had been named the "Pearl of Allah" by the Muslim tribal chief, because it resembled a turbaned head. Another even more elaborate legend says that this object is actually the Pearl of Lao-Tzu, a cultured pearl created with a carved amulet and then supposedly progressively grafted into several giant clams, before supposedly being lost due to a shipwreck in 1745. [6] This legend has been discredited, however because this pearl is indeed the product of a giant clam, Tridacna gigas, which cannot be grafted. The pearl is also a whole pearl, not a mabe pearl, and whole pearl culturing technology is only 100 years old. [7]


Different types of cultured pearls, including black pearls


Black pearls, frequently referred to as Black Tahitian Pearls, are highly valued because of their rarity; the culturing process for them dictates a smaller volume output and can never be mass produced. This is due to bad health and/or non-survival of the process, rejection of the nucleus and their sensitivity to changing climatic and ocean conditions. Before the days of cultured pearls, black pearls were rare and highly valued for the simple reason that white pearl oysters rarely produced naturally black pearls, and black pearl oysters rarely produced any natural pearls at all.

Since the development of pearl culture technology, the black pearl oyster found in Tahiti and many other Pacific Island areas has been extensively used for producing cultured pearls. The rarity of the black cultured pearl is now a "comparative" issue. The black cultured pearl is rare when compared to Chinese freshwater cultured pearls, and Japanese and Chinese akoya cultured pearls, and is more valuable than these pearls. However, it is more abundant than the South Sea pearl, which is more valuable than the black cultured pearl. This is simply because the black pearl oyster Pinctada margaritifera is far more abundant than the elusive, rare, and larger south sea pearl oyster - Pinctada maxima, which cannot be found in lagoons, but which must be dived for in a rare number of deep ocean habitats or grown in hatcheries.

Black cultured pearls from the black pearl oyster — Pinctada margaritifera — are not South Sea pearls, although they are often mistakenly described as black South Sea pearls. In the absence of an official definition for the pearl from the black oyster, these pearls are usually referred to as "black Tahitian pearls".

The correct definition of a South Sea pearl — as described by CIBJO and the GIA — is a pearl produced by the Pinctada maxima pearl oyster. South Sea pearls are the color of their host Pinctada maxima oyster — and can be white, silver, pink, gold, cream, and any combination of these basic colors, including overtones of the various colors of the rainbow displayed in the pearl nacre of the oyster shell itself.

Origin of a natural pearl


Previously natural pearls were found in many parts of the world. Present day natural pearling is confined mostly to seas off Bahrain. Australia also has one of the world's last remaining fleets of pearl diving ships. Australian pearl divers dive for south sea pearl oysters to be used in the cultured south sea pearl industry. The catch of pearl oysters is similar to the numbers of oysters taken during the natural pearl days. Hence significant numbers of natural pearls are still found in the Australian Indian Ocean waters from wild oysters. X-Ray examination is required to positively verify natural pearls found today.

Value of a natural pearl


Quality natural pearls are very rare jewels. The actual value of a natural pearl is determined in the same way as it would be for other "precious" gems. The valuation factors include size, shape, quality of surface, orient and luster.

Single natural pearls are often sold as a collector's item, or set as centerpieces in unique jewelry. Very few matched strands of natural pearls exist, and those that do often sell for hundreds of thousands of dollars. Yachtsman and financier Cartier purchased the landmark Cartier store on Fifth Avenue in New York for $100 cash and a double strand of matched natural pearls valued at $1 million.

Keshi pearls, although they often occur by chance, are not considered natural pearls. They are a byproduct of the culturing process, and hence do not happen without human intervention. These pearls are quite small: typically a few millimeters in size. Keshi pearls are produced by many different types of marine mollusks and freshwater mussels in China.[4] Today many "keshi" pearls are actually intentional, with post-harvest shells returned to the water to regenerate a pearl in the existing pearl sac.


Gemological identification


A well equipped gem testing laboratory (e.g. SSEF, Guebelin, GIA, AGTA, HIRCO-INDIA) is able to distinguish natural pearls from cultured pearls by using a gemological x-ray in order to examine the center of a pearl. With an x-ray it is possible to see the growth rings of the pearl, where the layers of calcium carbonate are separated by thin layers of conchiolin. The differentiation of natural pearls from tissue-nucleated cultured pearls can be very difficult without the use of this x-ray technique.

Natural and cultured pearls can be distinguished from imitation pearls using a microscope. Another method of testing for imitations is to rub the pearl against the surface of a front tooth. Imitation pearls are completely smooth, but natural and cultured pearls are composed of nacre platelets, which feel slightly gritty.

Cultured pearls


Cultured pearls (nucleated and non-nucleated or tissue nucleated cultured pearls) and imitation pearls can be distinguished from natural pearls by X-ray examination. Nucleated cultured pearls are often 'pre-formed' as they tend to follow the shape of the implanted shell bead nucleus. Once the pre-formed beads are inserted into the oyster, it secretes a few layers of nacre around the outside surface of the implant before it is removed after six months or more.

When a nucleated cultured pearl is X-rayed, it reveals a different structure to that of a natural pearl. A cultured pearl shows a solid center with no concentric growth rings, whereas a natural pearl shows a series of concentric growth rings.

Natural pearls


Natural pearls are nearly 100% calcium carbonate and conchiolin. It is thought that natural pearls form under a set of accidental conditions when a microscopic intruder or parasite enters a bivalve mollusk, and settles inside the shell. The mollusk, being irritated by the intruder, secretes the calcium carbonate and conchiolin to cover the irritant. This secretion process is repeated many times, thus producing a pearl. Natural pearls come in many shapes, with perfectly round ones being comparatively rare.

Creation of a pearl


The difference between natural and cultured pearls focuses on whether the pearl was created spontaneously by nature — without human intervention — or with human aid. Pearls are formed inside the shell of certain mollusks: as a defense mechanism to a potentially threatening irritant such as a parasite inside its shell, the mollusk creates a pearl to seal off the irritation.

The mantle of the mollusk deposits layers of calcium carbonate (CaCO3) in the form of the mineral aragonite or a mixture of aragonite and calcite (both crystalline forms of calcium carbonate) held together by an organic horn-like compound called conchiolin. The combination of aragonite and conchiolin is called nacre, which makes up mother-of-pearl. The commonly held belief that a grain of sand acts as the irritant is in fact rarely the case. Typical stimuli include organic material, parasites, or even damage that displaces mantle tissue to another part of the animal's body. These small particles or organisms enter the animal when the shell valves are open for feeding or respiration. In cultured pearls, the irritant is typically a cut piece of the mantle epithelium, together with processed shell beads, the combination of which the animal accepts into its body.

Freshwater and saltwater pearls


Freshwater and saltwater pearls may sometimes look quite similar, but they come from very different sources.

Natural freshwater pearls form in various species of freshwater mussels, family Unionidae, which live in lakes, rivers, ponds and other bodies of fresh water. These freshwater pearl mussels occur not only in hotter climates, but also in colder more temperate areas such as Scotland: see the freshwater pearl mussel. However, most freshwater cultured pearls sold today come from China.

Saltwater pearls grow within pearl oysters, family Pteriidae, which live in oceans. Saltwater pearl oysters are usually cultivated in protected lagoons or volcanic atolls.


Physical properties


The unique luster of pearls depends upon the reflection, refraction, and diffraction of light from the translucent layers. The thinner and more numerous the layers in the pearl, the finer the luster. The iridescence that pearls display is caused by the overlapping of successive layers, which breaks up light falling on the surface.

In addition, pearls (especially cultured freshwater pearls) can be dyed yellow, green, blue, brown, pink, purple, or black.


Definition of a pearl


Almost any shelled mollusk can, by natural processes, produce some kind of "pearl" when an irritating microscopic object becomes trapped within the mollusk's mantle folds, but the great majority of these "pearls" are not valued as gemstones. Nacreous pearls, the best-known and most commercially-significant pearls, are primarily produced by two groups of molluscan bivalves or clams. A nacreous pearl is made from layers of nacre, by the same living process as is used in the secretion of the mother of pearl which lines the shell.

A "natural pearl" is one that forms without any human intervention at all, in the wild, and is very rare. Many hundreds of pearl oysters or pearl mussels have to be gathered and opened, and thus killed, in order to find even one wild pearl, and for many centuries that was the only way pearls were obtained. This was the main reason why pearls fetched such extraordinary prices in the past. A cultured pearl, on the other hand, is one that has been formed on a pearl farm. In modern times however, almost all the pearls for sale were formed with the aid of human pearl farmers. The great majority of pearls on the market are cultured pearls.

One family of nacreous pearl bivalves, the pearl oysters, lives in the sea while the other, very different group of bivalves live in freshwater; these are the river mussels such as the freshwater pearl mussel. Saltwater pearls can grow in several species of marine pearl oysters in the family Pteriidae. Freshwater pearls grow within certain (but by no means all) species of freshwater mussels in the order Unionida, the families Unionidae and Margaritiferidae.

Pearl


A pearl is a hard, roundish object produced within the soft tissue (specifically the mantle) of a living shelled mollusk. Just like the shell of mollusks, a pearl is made up of of calcium carbonate in minute crystalline form, which has been deposited in concentric layers. The ideal pearl is perfectly round and smooth, but many other shapes of pearls (baroque pearls) occur. The finest quality natural pearls have been highly valued as gemstones and objects of beauty for many centuries, and because of this, the word pearl became a metaphor for something very rare, very fine, very admirable and very valuable.

Valuable pearls occur in the wild, but they are very rare. Cultured or farmed pearls make up the majority of those that are currently sold. Pearls from the sea are valued more highly than freshwater pearls. Imitation or fake pearls are also widely sold in inexpensive jewelry, but the quality of the iridescence is usually very poor, and generally speaking, fake pearls are usually quite easy to distinguish from the real thing. Pearls have been harvested, or more recently cultivated, primarily for use in jewelry, but in the past they were also stitched onto lavish clothing, as worn, for example, by royalty. Pearls have also been crushed and used in cosmetics, medicines, or in paint formulations.

In several European languages, the word "pearl" is synonymous with "bead", which can lead to confusion during translation.


Famous opals

The Andamooka Opal, presented to Queen Elizabeth II, also known as the Queen's Opal
The Aurora Australis Opal, considered to be the most valuable black opal
The Black Prince Opal, originally known as Harlequin Prince
The Empress of Australia Opal
The Fire Queen Opal
The Flame Queen Opal
The Flamingo Opal
The Halley's Comet Opal, the world's largest uncut black opal
The Jupiter Five Opal
The Olympic Australis Opal, reported to be the largest and most valuable uncut gem opal ever found
The Pride of Australia Opal, also known as the Red Emperor Opal
The Red Admiral Opal, also known as the Butterfly Stone
The Roebling Opal, Smithsonian Museum [12]


Historical superstitions


In the Middle Ages, opal was considered a stone that could provide great luck because it was believed to possess all the virtues of each gemstone whose color was represented in the color spectrum of the opal.[11] Victorian superstitions were created by the established gem dealers to stop the rush to buy opals. They paid an author to attribute bad luck to the stone, though some believed this is avoided if opal is the owner's birthstone or if the stone was a gift. Even as recently as under the last czar at the beginning of the 20th century, it was believed that when a Russian of any rank saw an opal among other goods offered for sale, he or she should not buy anything more since the opal was believed to embody the evil eye.[11] Opal is considered the birthstone for people born in October.

Non-crystalline opal


Two broad categories of non-crystalline opals, sometimes just referred to as "opal-A", have been proposed. The first of these is opal-AG consisting of aggregated spheres of silica, with water filling the space in between. Precious opal and potch opal are generally varieties of this, the difference being in the regularity of the sizes of the spheres and their packing. The second "opal-A" is opal-AN or water-containing amorphous silica-glass. Hyalite is another name for this.

Non-crystalline silica in siliceous sediments is reported to gradually transform to opal-CT and then opal-C as a result of diagenesis, due to the increasing overburden pressure in sedimentary rocks, as some of the stacking disorder is removed.[10]


Microcrystalline opal


Opal-CT has been interpreted as consisting of clusters of stacking of cristobalite and tridymite over very short length scales. The spheres of opal in opal-CT are themselves made up of tiny microcrystalline blades of cristobalite and tridymite. Opal-CT has occasionally been further subdivided in the literature. Water content may be as high as 10 wt%. Lussatite is a synonym. Opal-C, also called Lussatine, is interpreted as consisting of localized order of α-cristobalite with a lot of stacking disorder. Typical water content is about 1.5wt%.

Local atomic structure of opals


The lattice of spheres of opal that cause the interference with light are several hundred times larger than the fundamental structure of crystalline silica. As a mineraloid, there is no unit cell that describes the structure of opal. Nevertheless, opals can be roughly divided into those that show no signs of crystalline order (amorphous opal) and those that show signs of the beginning of crystalline order, commonly termed cryptocrystalline or microcrystalline opal.[9] Dehydration experiments and infrared spectroscopy have shown that most of the H2O in the formula of SiO2·nH2O of opals is present in the familiar form of clusters of molecular water. Isolated water molecules, and silanols, structures such as Si-O-H, generally form a lesser proportion of the total and can reside near the surface or in defects inside the opal.

The structure of low-pressure polymorphs of anhydrous silica consist of frameworks of fully-corner bonded tetrahedra of SiO4. The higher temperature polymorphs of silica cristobalite and tridymite are frequently the first to crystallize from amorphous anhydrous silica, and the local structures of microcrystalline opals also appear to be closer to that of cristobalite and tridymite than to quartz. The structures of tridymite and cristobalite are closely related and can be described as hexagonal and cubic close-packed layers. It is therefore possible to have intermediate structures in which the layers are not regularly stacked.


Synthetic opal

As well as occurring naturally, opals of all varieties have been synthesized experimentally and commercially. The discovery of the ordered sphere structure of precious opal led to its synthesis by Pierre Gilson in 1974.[5] The resulting material is distinguishable from natural opal by its regularity; under magnification, the patches of color are seen to be arranged in a "lizard skin" or "chicken wire" pattern. Synthetics are further distinguished from naturals by the former's lack of fluorescence under UV light. Synthetics are also generally lower in density and are often highly porous.

Two notable producers of synthetic opal are the companies Kyocera and Inamori of Japan. Most so-called synthetics, however, are more correctly termed "imitation opal", as they contain substances not found in natural opal (e.g., plastic stabilizers). The imitation opals seen in vintage jewelry are often "Slocum Stone" consisting of laminated glass with bits of foil interspersed.


Sources of opal


Australia produces around 97% of the world’s opal. 90% is called ‘light opal’ or white and crystal opal. White makes up 60% of the opal productions but cannot be found in all of the opal fields. Crystal opal or pure hydrated silica makes up 30% of the opal produced, 8% is black and only 2% is boulder opal.[citation needed]

The town of Coober Pedy in South Australia is a major source of opal. Andamooka in South Australia is also a major producer of matrix opal, crystal opal, and black opal. Another Australian town, Lightning Ridge in New South Wales, is the main source of black opal, opal containing a predominantly dark background (dark-gray to blue-black displaying the play of color). Boulder opal consists of concretions and fracture fillings in a dark siliceous ironstone matrix. It is found sporadically in western Queensland, from Kynuna in the north, to Yowah and Koroit in the south.[7]
 
Multi-colored rough opal specimen from Virgin Valley, Nevada, USA

The Virgin Valley opal fields of Humboldt County in northern Nevada produce a wide variety of precious black, crystal, white, fire, and lemon opal. The black fire opal is the official gemstone of Nevada. Most of the precious opal is partial wood replacement. Miocene age opalised teeth, bones, fish, and a snake head have been found. Some of the opal has high water content and may desiccate and crack when dried. The largest black opal in the Smithsonian Museum comes from the Royal Peacock opal mine in the Virgin Valley.[citation needed]

Another source of white base opal in the United States is Spencer, Idaho. A high percentage of the opal found there occurs in thin layers. As a result, most of the production goes into the making of doublets and triplets.

Other significant deposits of precious opal around the world can be found in the Czech Republic, Slovakia, Hungary, Turkey, Indonesia, Brazil, Honduras, Guatemala, Nicaragua and Ethiopia.

In late 2008, NASA announced that it had discovered opal deposits on Mars.[8]